By P. Hansen, P. W. Fowler, Maolin Zheng

This quantity comprises the court cases from the 1st DIMACS assembly on discrete mathematical chemistry held at Rutgers collage (New Brunswick, NJ). The contributions replicate the shows and highlight the breadth of present learn at the subject - from the Benzenoid Clar challenge to the Wulff-shape of sphere packings. a lot of the quantity displays the mixed mathematical and actual curiosity within the new molecules, fullerenes. This DIMACS convention highlighted the diversity of possibilities for fruitful and knowledgeable collaboration around the mathematics-chemistry limitations. The interdisciplinary nature of the contributions can pay testomony to the truth that 'real' chemistry and 'real' arithmetic do certainly have interaction.

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Additional info for Discrete Mathematical Chemistry: Dimacs Workshop, Discrete Mathematical Chemistry, March 23-24, 1998, Rutgers University

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10 m M ATP 4000 G I . . , Biochemistry Figure 3. X-band EPR spectra of Mn ' complexes with (Na* + K')-ATPase (21). lmM MnCU, and the concentrations of the substrates shown. ; ACS Symposium Series; American Chemical Society: Washington, DC, 1980.

W i l l vary w i t h the s t r e n g t h and symmetry of the l i g a n d f i e l d and w i l l express the dynamic process r e s p o n s i b l e f o r r e l a x a t i o n . This process could be e i t h e r the r o ­ t a t i o n of the complex ( t h i s would e s s e n t i a l l y be r o t a t i o n a l modulation of a s t a t i c z e r o - f i e l d s p l i t t i n g ) or symmetry f l u c t u ­ a t i o n s i n the complex due to d i s t o r t i o n s induced by the impact of solvent molecules ( i .

For comparison a fracture surface caused by cutting with scissors i s shown i n Figure 13. Figure 14 i s a fracture sur­ face produced after a sample was subjected at room temperature to an O 3 environment, at 90% strain for 6 days. The peripheral sur­ face of the fiber does not exhibit the blistered appearance pro­ duced by S O 2 and shown i n Figure 9 but does show a large number of microcracks. The microcracks on the fracture surface i n these figures are i n marked contrast to the comparatively "intact" frac­ ture of a sample held under 90% strain i n a i r and shown i n Figure 15.

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