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Additional resources for The Chemistry of Copper, Silver and Gold. Pergamon Texts in Inorganic Chemistry
Example text
Corfield and H. M. M. Shearer, Abs. Am. , p. 96. Bozeman, Montana (1964). 107 D. Blake, G. Calvin and G. E. Coates, Proc. Chem. Soc. (1959) 396. 108 H. Tropsch and W. J. Mattox, J. Am. Chem. Soc. 5 7 (1935) 1102. 109 R. M. Keefer and L. J. Andrews, / . Am. Chem. Soc. 7 0 (1948) 3261 ; ibid. 7 1 (1949) 2379, 2381, 3906 ; R. E. Kepner and L. J. A. Andrews, J. Org. Chem. 1 3 (1948) 208 ; J. Am. Chem. Soc. 7 1 (1949) 1723. no E. R. Gilliland, H. L. Bliss and C. E. Kip, / . Am. Chem. Soc. 6 3 (1941) 2088; E.
Nyholm, / . Chem. Soc. (1951) 1767. 1 50 G. W. Polly, D. E. Jackson and Β. E. Bryant, Inorg. Syntheses, 5 (1957) 16. 1 51 a M. B. Robin and P. Day, Advances in Inorg. Chem. and Radiochem. 10 (1967) 312. 1 5 b1 A. Ferrari, A. Braibanti and A. Tiripicchio, Acta Cryst. 21 (1966) 605. 41 CUPRIC HALIDES 7. C O P P E R ( I I ) COMPOUNDS The In this oxidation state copper has the electron configuration ls 2s 2p 3s 3p 3d . , but due to spin-orbit coupling higher values are often observed. M. M. g. in the cupric carboxylates) due to partial coupling of unpaired electrons between neighbouring copper atoms.
Chem. 2 (1963) 1210. G. B. Kauffman and L. A. Teter, Inorganic Syntheses, 7 (1900) 9. R. S. Nyholm, / . Chem. Soc. (1952) 1257. R. C. Cass, G. E. Coates and R. G. Hayter, / . Chem. Soc. 0955) 4007. K. Cohn and R. W. Parry, Inorg. Chem. 7 (1968) 46. most interesting system, and one which raises many unanswered questions concerning coordination numbers, is that containing the cuprous ion and ammonia. Many cuprous salts react with ammonia to give Cu(NH3)2-complexes ; even cuprous oxide will dissolve in either anhydrous or aqueous ammonia from which solutions solid complexes such as 9 8b C u ( N H 3 ) 2 N 0 3 , C u ( N H 3 ) 2 C 1 0 4 and C u ( N H 3 ) 2 I 0 3 have been isolated.