By Robert J. Hunter

Colloid technological know-how

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Smith, A. L. (1973). In "Dispersions of Powders in Liquids" Chapter 3. (G. D. ). , Barking. Sparnaay, M. J. (1972a). The electrical double layer In "Internat Encyclopaedia of Phys. Chem. and Chem. " Topic 14, Vol. 4 (D. H. ) Pergamon, Oxford and New York. Sparnaay, M. J. (1972b). J. Electroanal. Chem. 37, 65. Stern, O. (1924). Z. Elektrochem. 30, 508. Stigter, D. (1972). J. Electroanal. Chem. 37, 61. Stigter, D. (1975). J. Colloid Interface Sci. 53, 296. Stokes, A. N. (1976). J. Chem. Phys. 65, 261.

Elektrochem. 30, 508. Stigter, D. (1972). J. Electroanal. Chem. 37, 61. Stigter, D. (1975). J. Colloid Interface Sci. 53, 296. Stokes, A. N. (1976). J. Chem. Phys. 65, 261. Torrie, G. M. and Valleau, J. P. (1979). Chem. Phys. Letters 65, 343. Trasatti, S. (1971). J. Electroanal. Chem. 33, 351. van der Drift, W. P. J.

It may, however, be possible to apply these ideas to the liquid-liquid interface in emulsion systems. The more direct measurements of dielectric properties of interfaces, carried out by Dukhin (1970), show very large effects but the molecular dipoles referred to here probably play only a minor part in those situations. 3. The discreteness of charge effect The significance of this effect was first recognized by Frumkin (1933), and the first calculations of its magnitude were made by Esin and Shikov (1943) and Ershler (1946) in an attempt to explain the so-called Esin and Markov 2.

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