Download Polymer composite materials : from macro, micro to nanoscale by Abderrahim Boudenne PDF
By Abderrahim Boudenne
The contents of this ebook pay specific awareness to different length-scales (macro, micro and nano) as concerning acquiring a deeper knowing of the structure-property relationships of polymeric nanocomposite fabrics. They disguise significant findings and observations relating to the morphological, interfacial, processing reaction, actual and thermophysical houses of multiphase polymers and polymer Read more...
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Read Online or Download Polymer composite materials : from macro, micro to nanoscale : selected, peer reviewed papers from the Conference on Multiphase Polymers and Polymer Composites Systems: Macro to Nano Scales, June 7-10, 2011, Paris, France PDF
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Additional info for Polymer composite materials : from macro, micro to nanoscale : selected, peer reviewed papers from the Conference on Multiphase Polymers and Polymer Composites Systems: Macro to Nano Scales, June 7-10, 2011, Paris, France
Example text
TM-AFM phase images of (a) DO3-C500 and (b) DO3-C500ep11 after annealing at 110 ºC for 24 h (2 µm × 2 µm). The samples morphologies, generated by self-assembly of the BCP, were investigated using TM-AFM. In Fig. 2 TM-AFM phase images of the guest-host system DO3-C500 and the azocontaining block copolymer DO3-C500ep11 after annealing at 110 ºC for 24 h under vacuum can be observed. Both samples show a self-assembled cylindrical structure after the annealing treatment. In particular, most of PS cylinders are positioned parallel to the continuous phase of PB-block, where 11 mol% of PB is epoxidized for DO3-C500ep11.
Thus, the epoxidized PB block was able to react with the thermosetting formulation leading to nanostructured epoxy systems containing azobenzene groups, due to reaction induced microphase separation of polystyrene (PS) blocks. Optical and morphological properties of the resulting nanostructured materials were evaluated and discussed for different quantities of epoxidized SBS and various azobenzene concentrations in the epoxy matrix. Experimental Materials. An azo-chromophore, 4-(4-nitrophenylazo)aniline (O2N)(C6H4)N=N(C6H4)(NH2), Disperse Orange 3 (DO3), with a melting temperature of 200 ºC, was supplied by Aldrich.
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