By D. R. Paul (auth.), David E. Bergbreiter, Charles R. Martin (eds.)
This monograph includes manuscripts, poster abstracts and precis statements representing the contributions of a gaggle of scientists who participated within the 6th annual Texas A&M Industry-University Cooperative Chemistry software (IUCCP) at Texas A&M college in university Station, Texas, March 22-24, 1988. This symposium on "Functional Polymers" was once geared up by means of a university-industrial guidance committee including Dr. D. Keene, Hoechst Celanese; Dr. D. E. McLemore, Dow Chemical corporation; Dr. B. Frushour, Monsanto corporation; Dr. S. Corley, Shell improvement; Dr. F. Hoffstadt, BPAmerica; Dr. D. E. Bergbreiter, Texas A&M college; Dr. C. A. J. Hoeve, Texas A&M college; Dr. C. R. Martin, Texas A&M college; Dr. A. Clearfield, Texas A&M college; and Dr. A. E. Martell, Texas A&M college. The symposium itself was once generously supported by way of the commercial businesses engaging within the IUCCP application. those sponsoring chemical businesses comprise; Shell improvement corporation, Dow Chemical corporation, BPAmerica, Monsato corporation and Hoechst Celanese. the alternative of "Functional Polymers" because the topic for this symposium displays the swift advancements happening within the large box of polymer technological know-how and the possibility of utilizing polymeric derivatives in lots of new intriguing and very likely ecocnomic functions. The invited papers and submitted posters mirror the range of this box and comprise many alternative issues starting from biomedical purposes of polymers to carrying out polymers to take advantage of of polymers as lithographic mask and recording media. basic subject matters incorporated within the symposium have been: photoresponsive polymers, polymer blends, electronically conductive polymers, polymers catalysts, biomedical polymers and membrane delivery and permeability.
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J ~, ...... <>-- Stoich iomet ri c '..... ••. Blend \ ::J :::£ . ', Non· Stoichiometric', Blend 4+----------------------- -1 II -9 II 1118 TEMPERATURE 19 2l1JII ("C) Figure 4. 2 w/w) and a nonstoichiometric blend of S 0 P 0 0 - Acid (600 EW) / PEA-4VP (630 EW) (27/73 w/w). Experimental points are only shown for a stoichiometric blend of S 0 P 0 0 - Acid (600 EW)/PEA-4VP (630 EW) (49/51 w/w). exhibits a lower degree of miscibility enhancement, which is clearly apparent from the reappearance of the two-step descent of the storage modulus as well as the presence of a strong tano peak due to the ethyl acrylate component (Figures 4 and 5).
25. 26. ), Vol 1,Chapter 6,Viley,New York,1973. , MMI press. ,Gordon Breach Sci. Holden,J. , "Polymer Blends", Vol. ,"Anionic Polymerization, Kinetics Mechanics and Synthesis",ACS Symposium Series No. deGennes,J. Legge,"Thermoplastic Elastomers",Proc. ),Introduction 35 27. 28. 29. 30. 31. 32. Hashimoto,Polym. Meier,J. Appl. Polym. Byrd, paper presented at the Detroit meeting of the SPE,(RETECH),November,1982 MISCIBILITY ENHANCEMENT VIA IONIC INTERACTIONS IN THE PHENYLATED POLYPHENYLENE OXIDE/POLY(ETHYL ACRYLATE) BLEND SYSTEM R.
06 GPa. 15 GPa or 22 Ksi. At this temperature there is nearly a decade higher modulus that is attributable to the IPN structure over the matrix-disperse structure. The modulus of the three components and the IPN blend is shown as a function of temperature in Figure 6. The level of modulus corresponding to the HOT at 264 psi stress is shown by the dotted line. The IPN structure is helpful in significantly raising the HOT temperature over that of polypropylene in these polypropylene-polycarbonate blends.