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H. P. Seitsonen, Science 2002, 297, 2003. 1 Introduction Metal dusting is a catastrophic corrosion process leading to the disintegration of iron-, nickel- and cobalt-based alloys in strongly carburising gas atmospheres (carbon activity aC > 1) at moderately high temperatures (400–800°C). For iron-based alloys, the proposed mechanism [1–4] involves the super-saturation of iron with carbon and subsequent formation of cementite at the surface. This metastable cementite decomposes as the carbon activity in the cementite/ graphite interface is lowered to unity when graphite deposits on the cementite surface.
L. F. R. Walker, paper 2003-GT-38923 in Proc. 48th ASME Turbo Expo, ASME International, 2003. 15. P. J. L. E. Locci, JOM 1996; 8(11), 50. 16. C. H. K. Mallant, Fuel Cells Bulletin 2000, 3,5. 17. P. L. Adcock, M. J. Rowen, J. Appl. Electrochem. 2000, 30, 101. 18. H. Wang, M. A. Turner, J. Power Sources 2003, 115, 243. 19. L. Ma, S. A. Shores, J. New Mater. Electrochem. Sys. 2000, 3, 221. 20. J. Scholta, B. Rohland and J. Garche, in New Materials for Fuel Cell and Modern Battery Systems II, O. R.
The coating did not act as a water vapor barrier, with significant accelerated/non-protective SiO 2 growth evident below. Although these results indicate this approach is not promising for environmental barries coating EBC applications, self-graded oxide coatings were successfully formed from the deposited metallic precursor alloys, and there may be other applications where such an approach may be of interest. For the EBC application, a variation on conventional metallic coating strategy was subsequently investigated [13].